A combined experimental and theoretical study on the complexation of Li+ with valinomycin |
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| Authors: | Emanuel Makrlík Ji?í Dybal and Petr Vaňura |
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| Institution: | (1) Faculty of Applied Sciences, University of West Bohemia, Pilsen, Czech Republic;(2) Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, Prague, Czech Republic;(3) Institute of Chemical Technology, Prague, Czech Republic |
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| Abstract: | Abstract From extraction experiments in the two-phase water–nitrobenzene system and γ-activity measurements, the stability constant
of the valinomycin–lithium complex in nitrobenzene saturated with water was determined. Further, the structure of the resulting
complex was indicated by means of the density functional level of theory (DFT) calculations. |
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