Copolymerization of N,N-diallyl-N,N-dimethylammonium chloride and vinyl acetate |
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| Authors: | A I Vorob’eva D R Sagitova I R Aleev V P Volodina Yu A Prochukhan Yu B Monakov |
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| Institution: | 1. Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, pr. Oktyabrya 71, Ufa, 450054, Bashkortostan, Russia
2. Ufa State Academy of Economics and Service, ul. Chernyshevskogo 145, Ufa, 450078, Bashkortostan, Russia
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| Abstract: | The free-radical copolymerization of N,N-diallyl-N,N-dimethylammonium chloride with vinyl acetate in DMSO, methanol, and a methanol-water (70: 30, mol %) mixture proceeds to yield statistical copolymers. The nature of solvents significantly affects the reactivity ratios of the comonomers. N,N-Diallyl-N,N-dimethylammonium chloride shows a higher reactivity than vinyl acetate. The kinetic features of the processes have been investigated, and the structure and properties of the copolymers have been studied. |
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