Dynamics of lithium electrode passivation in aprotic organic electrolytes,studied by electrochemical noise method |
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Authors: | L. S. Kanevskii B. M. Grafov |
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Affiliation: | (1) Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia |
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Abstract: | Lithium electrode passivation is studied in different organic electrolytes, namely, 1 M LiClO4 in 1,3-dioxolane, 1 M LiN(CF3SO2)2 in 1,3-dioxolane, 1 M LiPF6 in an ethylene carbonate-diethyl carbonate mixture, 1 M LiPF6 in an ethylene carbonate-dimethyl carbonate mixture, using the electrochemical noise method. The dynamics of passive film formation on the lithium surface in the mentioned electrolytes that differ in their corrosivity towards lithium is followed. |
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Keywords: | electrochemical noise lithium electrode electrode passivation aprotic organic electrolytes |
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