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A calibration method for broad-bandwidth cavity enhanced absorption spectroscopy performed with supercontinuum radiation
Authors:T Laurila  I S Burns  J Hult  J H Miller  C F Kaminski
Institution:(1) Institute of Optics and Electronics, Chinese Academy of Sciences, P.O. Box 350, Shuangliu, Chengdu, 610209, P.R. China;(2) Graduate School of the Chinese Academy of Sciences, Beijing, 100039, P.R. China;
Abstract:An efficient calibration method has been developed for broad-bandwidth cavity enhanced absorption spectroscopy. The calibration is performed using phase shift cavity ring-down spectroscopy, which is conveniently implemented through use of an acousto-optic tunable filter (AOTF). The AOTF permits a narrowband portion of the SC spectrum to be scanned over the full high-reflectivity bandwidth of the cavity mirrors. After calibration the AOTF is switched off and broad-bandwidth CEAS can be performed with the same light source without any loss of alignment to the set-up. We demonstrate the merits of the method by probing transitions of oxygen molecules O2 and collisional pairs of oxygen molecules (O2)2 in the visible spectral range.
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