Catalytic hydroamination of furfuryl and tetrahydrofurfuryl alcohols with nitriles |
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| Authors: | S I Kozintsev L I Basalaeva L V Gladkikh N S Kozlov |
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| Institution: | (1) Institute of Physical Organic Chemistry, Academy of Sciences of the Belorussian SSR, 220603 Minsk |
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| Abstract: | Reaction of furfuryl and tetrahydrofurfuryl alcohols with nitriles over copper oxide catalysts under a hydrogen pressure of 15 atm at a temperature of 230 C gives N-alkylfurfuryl- (yield 46–50%) and N-alkyl-tetrahydrofurfurylamines (49–53%), and N-alkylpiperidines (28–41%). A reaction mechanism is proposed.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 23–26, January, 1988. |
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