Four-electron reduction of dinitrogen during solution disproportionation of the organodimetallic (eta-C5Me4R)2Ta2(mu-Cl)4(R = Me, Et) to a new mu-eta1,eta1-N2 complex and odd-electron organotrimetallic cluster |
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| Authors: | Lee Ting-Yu Wooten Alfred J Luci Jeffrey J Swenson Dale C Messerle Louis |
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| Institution: | Department of Chemistry, University of Iowa, Iowa City, Iowa 52242, USA. |
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| Abstract: | (C5Me5R)2Ta2Cl4 (d2-d2) disproportionates under dinitrogen to (C5Me4R)TaCl2]2(mu-N2) and the D3h cluster cation (C5Me4R)3Ta3(mu-Cl)6+ with anionic (C5Me4R)TaCl4-. |
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