| A new method of immobilizing ionic liquids into layered zirconium phosphates |
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| 作者姓名： | Hai Yan Wang Da Xiong Han The Key Laboratory of Global Change and Marine-Atmopheric Chemistry Third Institute of Oceanography of State Oceanic Administration Xiamen China |
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| 作者单位： | Hai Yan Wang，Da Xiong Han The Key Laboratory of Global Change and Marine-Atmopheric Chemistry，Third Institute of Oceanography of State Oceanic Administration，Xiamen 361005，China Department of Pharmacy，Medical College of Xiamen University，Xiamen 361005，China |
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| 摘 要： | In this work, a new method of a series of ion liquids (ILs) 1-alkyl-3-methylimidazolium chloride Cnmim]Cl (n = 2, 4, 6, 8) intercalation into layered zirconium phosphates was investigated. It was found that theα-ZrP-2BA (i.e. pre-intercalated BA was arranged in a bilayer mode in the galleries ofα-ZrP) was a suitable host for intercalation ILs: ILs was inserted through exchanging pre-intercalated BA. And the intercalation orientation was investigated by use of X-ray diffraction (XRD) experiments and molecular modeling calculation.
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| 收稿时间： | 13 November 2006 |
A new method of immobilizing ionic liquids into layered zirconium phosphates |
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| Hai Yan Wang,Da Xiong Han The Key Laboratory of Global Change and Marine-Atmopheric Chemistry,Third Institute of Oceanography of State Oceanic Administration,Xiamen ,China.A new method of immobilizing ionic liquids into layered zirconium phosphates[J].Chinese Chemical Letters,2007,18(6):764-767. |
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| Authors: | Hai Yan Wang Da Xiong Han |
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| Institution: | 1. The Key Laboratory of Global Change and Marine-Atmopheric Chemistry, Third Institute of Oceanography of State Oceanic Administration, Xiamen 361005, China;2. Department of Pharmacy, Medical College of Xiamen University, Xiamen 361005, China |
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| Abstract: | In this work, a new method of a series of ion liquids (ILs) 1-alkyl-3-methylimidazolium chloride Cnmim]Cl (n = 2, 4, 6, 8) intercalation into layered zirconium phosphates was investigated. It was found that the α-ZrP·2BA (i.e. pre-intercalated BA was arranged in a bilayer mode in the galleries of α-ZrP) was a suitable host for intercalation ILs: ILs was inserted through exchanging pre-intercalated BA. And the intercalation orientation was investigated by use of X-ray diffraction (XRD) experiments and molecular modeling calculation. |
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| Keywords: | Ionic liquids Zirconium phosphates Intercalation |
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