|
|||||
|
|
Configurational assignment of N-arylsulfonylimines of alpha-polychloroaldehydes |
|
| Authors: | Krivdin Leonid B Chernyshev Kirill A Rosentsveig Gulnur N Ushakova Irina V Rosentsveig Igor B Levkovskaya Galina G |
| Affiliation: | A. E. Favorsky Institute of Chemistry, Irkutsk, Siberian Branch of the Russian Academy of Sciences, Favorsky St. 1, 664033 Irkutsk, Russia. krivdin.office@irioch.irk.ru |
| Abstract: | Configurational assignment of seven synthesized N-arylsulfonylimines of alpha-polychloroaldehydes has been carried out by means of experimental measurements and high-level ab initio calculations of their (13)C--(13)C, (13)C--(1)H and (15)N--(1)H spin-spin coupling constants. The title compounds were shown to exist in solution solely in the form of E isomers, in line with thermodynamic reasoning. |
| Keywords: | NMR spin–spin coupling constant SOPPA configurational assignment N‐arylsulfonylimines of polychloroaldehydes |
| 本文献已被 PubMed 等数据库收录！ | |