The influence of polychromic light on the surface of MDI based polyurethane elastomer |
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Authors: | Dan Rosu Constantin Ciobanu Liliana Rosu Carmen-Alice Teaca |
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Institution: | a“Petru Poni” Institute of Macromolecular Chemistry, 41A Gr. Ghica-Voda Alley, Iasi, 700487 Romania |
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Abstract: | A polyurethane elastomer was synthesized starting from 4,4′ diphenylmethane diisocyanate and poly(ethyleneadipate)diol. Butylene glycol was used as chain extender. Surface properties after photo-degradation of the elastomer under the action of the radiation with λ > 300 nm was monitored by FT-IR spectroscopy and contact angle measurements. The quality of polymer surface was observed under optical microscope. The formation of photo-Fries rearrangement and Norrish II reaction products during irradiation was associated with the gloss loss (from 100% for non-irradiated sample to 27% after 200 h irradiation time) and modification of wettability. There were also found significant modifications with irradiation time of both the glass transition temperature (Tg decreases from 64 °C for non-irradiated sample to 53 °C after 200 h irradiation) and the swelling coefficient (an increase from 1.2% up to 2.5% is observed after 200 h irradiation). |
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Keywords: | Polyurethane UV-irradiation FT-IR spectroscopy Gloss Contact angle Glass transition temperature |
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