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Rhodium catalysed tandem conjugate addition-protonation: an enantioselective synthesis of 2-substituted succinic esters
Authors:Moss Rebecca J  Wadsworth Kelly J  Chapman Christopher J  Frost Christopher G
Affiliation:Department of Chemistry, University of Bath, Claverton Down, Bath, UK BA2 7AY.
Abstract:The rhodium catalysed addition of potassium trifluoro(organo)borates to dimethyl itaconate generates an intermediate complex which on protonation provides enantioenriched succinic esters.
Keywords:
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