Rhodium catalysed tandem conjugate addition-protonation: an enantioselective synthesis of 2-substituted succinic esters |
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Authors: | Moss Rebecca J Wadsworth Kelly J Chapman Christopher J Frost Christopher G |
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Affiliation: | Department of Chemistry, University of Bath, Claverton Down, Bath, UK BA2 7AY. |
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Abstract: | The rhodium catalysed addition of potassium trifluoro(organo)borates to dimethyl itaconate generates an intermediate complex which on protonation provides enantioenriched succinic esters. |
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