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生物降解原油研究的新方法
引用本文:朱军,李术元,郭绍辉.生物降解原油研究的新方法[J].燃料化学学报,2003,31(1):1-5.
作者姓名:朱军  李术元  郭绍辉
作者单位:State Key Lab of Heavy Oil Processing, University of Petroleum, Beijing 102200, China
基金项目:国家自然科学基金(40172048)
摘    要:利用沥青质包裹烃和沥青质钌离子催化氧化(RICO)产物中的生标对生物降解原油进行了研究。研究表明,虽然原油中的生标受到了严重破坏,但利用这两种方法在沥青质中均可以获得较为完整的生标系列。与其它方法相比,这两种方法简单方便,结果较为可靠、准确,可能是生物降解原油研究的发展方向。

关 键 词:生物降解原油  沥青质  包裹烃  钌离子催化氧化  生物标记物  
文章编号:0253-2409(2003)01-0001-05
收稿时间:2002-09-12
修稿时间:2002年9月12日

NEW METHODS FOR THE STUDY OF BIODEGRADED CRUDE OIL
ZHU Jun,LI Shu-yuan,GUO Shao-hui.NEW METHODS FOR THE STUDY OF BIODEGRADED CRUDE OIL[J].Journal of Fuel Chemistry and Technology,2003,31(1):1-5.
Authors:ZHU Jun  LI Shu-yuan  GUO Shao-hui
Abstract:Entrapped hydrocarbons from asphaltene and products from the ruthenium ions catalyzed oxidation (RICO) of asphaltene were used to study the biodegraded crude oil. The results indicate that the biomarkers, which are almost destroyed by biodegradation in the oil, can be recoveried from asphaltene by these two methods. A fairly intergrate series of hopanes and steranes are discovered in the entrapped hydrocarbons, and a homologous series of hopanoic and steranoic acids are also detected in the RICO products. Compared with other methods, these methods are simple and convenient, and the results obtained are credible and accurate. Hence, these new methods are significant for the study of biodegraded crude oil.
Keywords:biodegraded crude oil  asphaltene  entrapped hydrocarbons  RICO  biomarkers
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