| 用^19F NMR方法测 定光学活性胺与醇的光学纯度 |
| |
| 引用本文： | 陆亨尧. 用^19F NMR方法测 定光学活性胺与醇的光学纯度[J]. 有机化学, 1985, 5(2): 140-143 |
| |
| 作者姓名： | 陆亨尧 |
| |
| 作者单位： | 中国科学院上海有机化学研究所 |
| |
| 摘 要： | 本文研究了全氟-2-正丙氧基丙酸的某些非对映异构体酯与酰胺在~(19)FNMR上化学位移的差别,应用这种差别可确定光学活性醇与胺的光学纯度。
|
| 关 键 词： | 核磁共振谱法 化学位移 手征性 氟化合物。 |
19F NMR NONEQUIVALENCE OF DIASTEREOMERIC ESTERS AND AMIDES FOR THE DETERMINATION OF ENANTIOMERIC PURITY |
| |
| Lu Hengyao. 19F NMR NONEQUIVALENCE OF DIASTEREOMERIC ESTERS AND AMIDES FOR THE DETERMINATION OF ENANTIOMERIC PURITY[J]. Chinese Journal of Organic Chemistry, 1985, 5(2): 140-143 |
| |
| Authors: | Lu Hengyao |
| |
| Affiliation: | Lu Hengyao Shanghai Institute of Organic Chemistry,Academia Sinica |
| |
| Abstract: | ~(19)F NMR spectra of some of the diastereomeric derivatives of perfluoro-2-propoxypropionic acid were determined,and the chemical shift differences between dias-tereomers were used to determine the enantiomeric purities of chiral amines and alcohols. |
| |
| Keywords: | nuclear magnetic resonance spectrometry chemical shift chirality fluorine compounds. |
| 本文献已被 CNKI 等数据库收录！ |
| 点击此处可从《有机化学》浏览原始摘要信息 |
|
点击此处可从《有机化学》下载全文 |
