Iron chemistry of an asymmetrically substituted,triazole-functionalised calixarene ligand |
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| Authors: | Michaela Ritter Anat Molad Varun Rawat Christian Limberg |
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| Affiliation: | 1. Department of Chemistry, Humboldt-Universit?t zu Berlin, Berlin, Germany;2. The Raymond and Beverly Sackler Faculty of Exact Sciences, School of Chemistry, Tel Aviv University, Tel Aviv 69978, Israel |
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| Abstract: | The synthesis and characterisation of an asymmetrically substituted calix-triazole ligand are reported. The ligand reacts with the Fe(II) precursor Fe2Mes4 to yield an iron(II) calixarene complex that is oxidised by dioxygen to provide a dinuclear Fe(III) compound featuring an oxido bridge. |
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| Keywords: | calixarene cross-coupling metal complexes triazole |
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