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Optically Active T-Butylphenylphosphinothioic Acid: Synthesis,Selected Structural Studies and Applications as a Chiral Solvating Agent |
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| Authors: | Józef Drabowicz Patrycja Pokora-Sobczak Dorota Krasowska Zbigniew Czarnocki |
| Affiliation: | 1. Center of Molecular and Macromolecular Studies, Polish Academy of Sciences, Department of Heteroorganic Chemistry, Sienkiewicza, Poland;2. Jan Dlugosz University in Czestochowa, Institute of Chemistry, Environmental Protection and Biotechnology, Czestochowa, Polanddraj@cbmm.lodz.pl;4. Faculty of Chemistry, Warsaw University, Warsaw, Poland |
| Abstract: | AbstractSynthesis, structural studies and the use of the (?)-(S)- and (+)-(R) enantiomers of t-butylphenylphosphinothioic acid as a chiral solvating agent for the determination of enantiomeric purity is discussed. Systems that are the most extensively studied are emphasized. |
| Keywords: | NMR spectroscopy chiral solvating agents enantiomeric excess enantiomeric purity |