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Multiplurifunctionalized Phosphorus Dendrimers: Selective Functionalization of P(X)CL2 Terminal Groups
Authors:Anne-Marie Caminade  Jean-Pierre Majoral
Institution:1. CNRS, Laboratoire de Chimie de Coordination (LCC), 205 route de Narbonne, BP 44099 F-31077, Toulouse Cedex 4, France;2. Université de Toulouse, UPS, INPT, F-31077, Toulouse Cedex 4, Francecaminade@lcc-toulouse.fr;4. Université de Toulouse, UPS, INPT, F-31077, Toulouse Cedex 4, France
Abstract:Abstract

Dendrimers are hyperbranched macromolecules constituted of repetitive branched units. They are synthesized step-by-step, a method which ensures a perfectly defined structure. This mini-review reports examples of rare “multiplurifunctionalized” dendrimers that have several types of functional groups precisely located on each terminal branching point. They are obtained thanks to the specificity of the reactivity of each Cl of P(X)Cl2 (X = generally S, but also O) terminal groups on the surface of poly(phosphorhydrazone) dendrimers.
Keywords:Dendrimers  phosphorhydrazone  functionalization
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