Character of interaction and glass formation in the TlAs2Se4-Tl3As2S3Se3 system |
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Authors: | I. I. Aliev I. G. Aliev A. A. Farzaliev Dzh. A. Veliev |
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Affiliation: | (1) Institute of Chemical Problems, H. Javid ave. 29, Baku, 370143, Azerbaijan;(2) Harran University, Sanliurfa, Turkey |
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Abstract: | The TlAs2Se4-Tl3As2S3Se3 system was investigated by physicochemical methods (DTA, X-ray powder diffraction, microstructural analysis), and its phase diagram was constructed. The TlAs2Se4-Tl3As2S3Se3 join is a quasi-binary internal section of the As-Tl-S-Se quaternary system. The solubility range of TlAs2Se4-based solid solutions is extended to 7 mol %, and the region of Tl3As2S3Se3-based solid solutions is extended to 15 mol %. |
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