Synthesis of a green [60]fullerene derivative through cage-opening reactions |
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Authors: | Liu Shuming Zhang Changqi Xie Xiang Yu Yuming Dai Zhifei Shao Yuanhua Gan Liangbing Li Yuliang |
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Institution: | Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China. |
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Abstract: | Open-cage derivative C(60)(O)(4)(OH)(2)(NC(6)H(4)(t)Bu)(2) reacts with ICl to form a Baeyer-Villiger type product, which yields an intense green product upon treatment with HI. |
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