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First C-3 lithiation of DMAP: a new entry into chemical tuning of acylation catalysts |
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| Authors: | Gros Philippe C Doudouh Abdelatif Woltermann Christopher |
| Institution: | Synthèse Organométallique et Réactivité, UMR CNRS-UHP 7565 Université Henri Poincaré, Faculté des Sciences, Boulevard des Aiguillettes, 54506 Vandoeuvre-lès-Nancy, France. philippe.gros@sor.uhp-nancy.fr |
| Abstract: | A TMSCH2Li-based reagent promoted the first C-3 lithiation of DMAP opening a direct access to functional diversity in acylation catalysts. |
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