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The sorption mechanism of Au(III) on sulfur-containing chelating resin poly[4-vinylbenzyl (2-hydroxyethyl) sulfide]
Authors:Rongjun Qu  Changmei Sun  Chunnuan Ji  Chunhua Wang
Institution:a School of Chemistry and Materials Science, Yantai Normal University, Yantai 264025, PR China
b School of Materials Science and Engineering, Tianjin University, Tianjin 300072, PR China
Abstract:The sorption mechanism of sulfur-containing chelating resin, poly4-vinylbenzyl (2-hydroxyethyl) sulfide], towards Au(III) was investigated by Fourier transform infrared spectra (FTIR), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), energy dispersive X-ray microanalysis (EDX), and X-ray diffraction (XRD). It was showed that the sulfide bond in the resin was oxidized into sulfoxide and sulfone bond, and Au(III) was deoxidized into Au(0).
Keywords:Poly[4-vinylbenzyl (2-hydroxyethyl) sulfide]  Sorption mechanism  Au(III)  Redox
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