| The Selective Reduction of 4-Propylthio-2-nitroaniline with CO Using Ru3（CO）12／PEDPA Complex as Catalyst |
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| 作者姓名： | JingYangJIANG QiangMIAO YanHuaWANG ZiLinJIN |
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| 作者单位： | StateKeyLaboratoryofFineChemicals,DalianUniversityofTechnology,Dalian116012 |
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| 摘 要： | The Ru3(CO)12/PEDPA complex was firstly applied in the CO selective reduction of 4-propylthio-2-nitroaniline.The effects of reaction temperature,the pressure of CO and concentration of catalyst on the reduction were investigated.Under the optimum conditions of T=140℃, Pco=5.0MPa and substrate/catalyst=300(molar ratio),the conversion and selectivity were 70% and 98%,respectively.After simple phase separation,the catalyst could be recycled.
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| 关 键 词： | 一氧化碳 选择还原 4-丙基硫代-2-硝基苯胺 Ru3（CO）12 催化剂 PEDPA |
The Selective Reduction of 4-Propylthio-2-nitroaniline With CO Using Ru3(CO)12/PEDPA Complex as Catalyst |
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| JingYangJIANG QiangMIAO YanHuaWANG ZiLinJIN.The Selective Reduction of 4-Propylthio-2-nitroaniline With CO Using Ru3(CO)12/PEDPA Complex as Catalyst[J].Chinese Chemical Letters,2004,15(4):394-396. |
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| Authors: | Jing Yang JIANG Qiang MIAO Yan Hua WANG Zi Lin JIN State Key Laboratory of Fine Chemicals Dalian University of Technology Dalian |
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| Institution: | Jing Yang JIANG,Qiang MIAO,Yan Hua WANG,Zi Lin JIN State Key Laboratory of Fine Chemicals,Dalian University of Technology,Dalian 116012 |
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| Abstract: | |
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| Keywords: | CO selective reduction 4-propylthio-2-nitroaniline Ru3(CO)_(12) phosphine |
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