Transformations of diepoxy derivatives of limonene in homogeneous acidic media |
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| Authors: | O V Salomatina O I Yarovaya D V Korchagina Yu V Gatilov M P Polovinka V A Barkhash |
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| Institution: | (1) Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090, Russia |
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| Abstract: | Transformations of diepoxy derivatives of limonene under conditions of homogeneous acid catalysis were studied, and their results were compared with those obtained over heterogeneous catalysts. A number of previously unknown compounds were isolated. The most possible transformation pathways were analyzed by computer simulation using molecular-mechanics and quantum-chemical methods. |
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