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Synthesis of N-confused porphyrin derivatives with a substituted 3-C position
Authors:Li Xiaofang  Liu Bin  Yi Pinggui  Yi Rongqiong  Yu Xianyong  Chmielewski Piotr J
Institution:Key Laboratory of Theoretical Chemistry and Molecular Simulation of Ministry of Education, Hunan Province College Key Laboratory of QSAR/QSPR, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, Hunan 411201, China.
Abstract:Active methylene compounds such as 5,5-dimethylcyclohexane-1,3-dione, cyclohexane-1,3-dione, 3-methyl-1-phenyl-1H-pyrazol-5(4H)-one, 1,3-dimethyl-1H-pyrazol-5(4H)-one, and 3-methylisoxazol-5(4H)-one react with the 3-C position of N-confused porphyrin in THF for 5 min to afford a novel type of N-confused porphyrin derivatives in good yield without the need of any catalyst.
Keywords:
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