Systematic atomic number effects in complexes exhibiting ligand luminescence: Part 2. Salicylidene-o-aminophenolates |
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| Authors: | TL Craven FE Lytle |
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| Institution: | Department of Chemistry, Purdue University, West Lafayette, Indiana 47907 U.S.A. |
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| Abstract: | The room-temperature fluorescence properties of Group IIIA metal complexes with salicylidene-o-aminophenol (SoAP) in aqueous 20% methanol are reported. The data include absorption, emission and excitation maxima, quantum yields and luminescence lifetimes. A systematic heavy atom effect influences the fluorescence decay to an extent sufficient for simultaneous kinetic analysis of ternary metal ion mixtures, based on decayrate measurements. |
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