| Chemoselective Reduction of Azides to Amines Using Sm/TMSCl System in the Presence of Trace Amounts of Water |
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| 引用本文： | Jin Chang DING*,Hua Yue WU Department of Chemistry,Wenzhou Normal College,Wenzhou 325027. Chemoselective Reduction of Azides to Amines Using Sm/TMSCl System in the Presence of Trace Amounts of Water[J]. 中国化学快报, 2001, 0(8) |
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| 作者姓名： | Jin Chang DING* Hua Yue WU Department of Chemistry Wenzhou Normal College Wenzhou 325027 |
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| 作者单位： | Jin Chang DING*，Hua Yue WU Department of Chemistry，Wenzhou Normal College，Wenzhou 325027 |
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| 摘 要： | Samarium diiodide and organosamarium compounds have been widely employed as useful reagents in organic synthesis1. However, relatively few reports on the direct use of samarium metal in organic synthesis have been reported2, because the surface of samarium metal is inactive3. In order to improve the activity of samarium, some additives, such as HgCl24, NH4Cl (aq.)5, or TMSCl6 were added.The reduction of azides to the corresponding amines is an important reaction in organic synthesis7-16. A…
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Chemoselective Reduction of Azides to Amines Using Sm/TMSCl System in the Presence of Trace Amounts of Water |
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| Jin Chang DING,Hua Yue WU. Chemoselective Reduction of Azides to Amines Using Sm/TMSCl System in the Presence of Trace Amounts of Water[J]. Chinese Chemical Letters, 2001, 0(8) |
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| Authors: | Jin Chang DING Hua Yue WU |
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| Affiliation: | Jin Chang DING*,Hua Yue WU Department of Chemistry,Wenzhou Normal College,Wenzhou 325027 |
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| Abstract: | Azides can be easily reduced to the corresponding amines with Sm/TMSCl/H2O (trace) system in excellent yields under mild and neutral conditions. |
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| Keywords: | Azides amines Sm/TMSCl/H2O(trace)system. |
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