Novel series of clathrate compounds of the three-dimensional metal complex hosts (N-methyl-1,3-diaminopropane)cadmium(II) tetracyanonickelate(II), (N,N-Dimethyl-1,3-diaminopropane)cadmium(II) Tetracyanonickelate(II), and (2-Hydroxyethylmethylamine) cadmium(II) Tetracyanonickelate(II) |
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| Authors: | Shinachi Nishikiori Yuhko Takahashi-Ebisudani Toschitake Iwamoto |
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| Institution: | (1) Department of Chemistry, College of Arts and Sciences, The University of Tokyo, Komaba, Meguro, 153 Tokyo, Japan |
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| Abstract: | The clathrate compounds of the title three-dimensional metal complex hosts have been prepared with various aliphatic, alicyclic, and aromatic guest molecules. The typical structure has been demonstrated for a cyclohexane clathrate (N-methyl-1,3-diaminopropane)cadmium(II) tetracyanonickelate(II)-cyclohexane(2/1) by X-ray single crystal analysis. The powder X-ray diffraction data were assigned for the other clathrates to the tetragonal systems isostructural to the cyclohexane clathrate in which the box-like cavity with the approximate dimensions of 7 × 7 × 5 Å3 accommodates the guest molecule. |
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| Keywords: | Alicyclic guest aliphatic guest aromatic guest cadmium crystal structure cyclohexane 2-hydroxyethylmethylamine N N-dimethyl-1 3-diaminopropane N-methyl-1 3-diaminopropane tetracyanonickelate(II) |
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