Direct observation of enantioselective synergism at trimetallic centers |
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| Authors: | Gao Jian Zingaro Ralph A Reibenspies Joseph H Martell Arthur E |
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| Affiliation: | Department of Chemistry, Texas A and M University, College Station, Texas 77843-3255, USA. gaoj2@uthscsa.edu |
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| Abstract: | [structure: see text] [structure: see text] New oligomeric chiral macrocyclic ligands have been synthesized using an efficient self-assembly method. High enantioselective cooperativity in the catalytic asymmetric aldol reactions was directly observed using the conceptually novel chiral multinuclear complex catalysts. |
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