| Synthesis and Crystal Structure of Chiral Spiro{1-bromo-4-hydroxy-5-N-cyclohexyl- butyrolactam-6-oxo-dirings[3.1.0]hexane-2,3＇- （4＇-diphenylcarbinol-5＇-menthyloxy-butyrolatone） } |
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| 作者姓名： | WANG Jian-Ge, QIN Jian-Hua, WANG Jian-Ping, LI Ying-Fei, LI Hua-Min |
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| 作者单位： | [1]College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, China [2]Chemical Engineering ＆ Pharmaceutics College, Henan University of Science and Technology, Luoyang 471003, China [3]College of Chemistry, Beijing Normal University, Beijing 100875, China |
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| 基金项目： | Supported by the Key Subject of Luoyang Normal University （No. 2004yzk90） |
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| 摘 要： | A novel compound of chiral spiro{1-bromo-4-hydroxy-5-N-cyclohexyl-butyro-lactam-6-oxo-dirings[3.1.0]hexane-2,3＇-（4＇-diphenylcarbinol-5＇-menthyloxy-butyrolatone）} was synthesized via tandem nucleophilic substitution reaction under mild conditions, and its structure was determined by IR, ^1H NMR, elemental analysis and X-ray diffraction. The crystal structure of this compound is of monoclinic system, space group P21 with a = 9.7356（9）, b = 12.2760（12）, c = 14.9577（14） A, β = 101.0300（10）°, Mr = 680.66, Z = 2, V = 1754.6（3） A^3, Dc = 1.288 g/cm^3, p（MoKα） = 1.216 mm^-1, F（000） = 716, the final R = 0.0434 and wR = 0.0996.
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| 关 键 词： | 均衡分析 晶体结构 螺环烃 手征性 |
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