The vibrational structure of the electronic spectra of quinoxaline in shpolskii-type hydrocarbon matrices |
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Authors: | K. Brenner Z. Ruziewicz |
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Affiliation: | Physical Chemistry Laboratory, Institute of Organic and Physical Chemistry, Technical University, Wroclaw, Poland |
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Abstract: | Quasilinear spectrum of the S1(n, π1, 1B1) ← S0 transition of quinoxaline in crystalline methylcyclohexane matrix and quasilinear phosphorescence spectra of quinoxaline in high- and low-temperature modifications of isooctane matrix were obtained at 77 K. The results of a full vibrational analysis of the spectra are presented and discussed. The diffuseness of the absorption spectrum in the range 3200-2900 Å is ascribed essentially to a small energy gap between the S2 and S3 states. The activity of out-of-plane vibration, 865 cm-1, in the phosphorescence and the influence of matrices on the structure of the spectra suggest the possibility of out-of-plane distortion of the quinoxaline molecule in the T1 state. |
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