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1-Substituted 5-thiotetrazoles as novel capping agents for stabilization of gold nanoparticles
Authors:Maria N. Nichick   Sergei V. Voitekhovich   Alexey Shavel   Anatoly I. Lesnikovich  Oleg A. Ivashkevich
Affiliation:aResearch Institute for Physical Chemical Problems of Belarusian State University, 220030 Minsk, 14 Leningradskaya Str., Belarus;bDepartamento de Quimica Fisica and Unidad Asociada CSIC, Universidade de Vigo, 36310 Vigo, Spain
Abstract:Stable and nearly monodispersed gold nanoparticles with sizes of 2.8–4.7 nm are easily prepared by the reduction of tetrachloroaurate salts in a toluene-water system in the presence of 1-R-5-thiotetrazoles (R = Et, t-Bu, 1-adamatyl). The prepared gold nanoparticles were characterized by TEM, XRD, UV–Vis, FTIR and TGA.
Keywords:Gold nanoparticles   Tetrazoles   Capping agents   Reduction
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