| ⅥB族金属叁键有机化合物的研究进展 |
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| 引用本文： | 宋礼成,王吉泉.ⅥB族金属叁键有机化合物的研究进展[J].有机化学,1994(3). |
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| 作者姓名： | 宋礼成 王吉泉 |
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| 作者单位： | 南开大学化学系，南开大学化学系 天津，300071，天津，300071 |
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| 基金项目： | 国家自然科学基金及元素有机国家重点实验室资助课题 |
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| 摘 要： | 本文对一类重要的ⅥB族金属叁键化合物R_2M_2(CO)_4(R为环戊二烯基及类环戊二烯基)近年来的研究成果进行了综述,综述重点是这类化合物的官能团M≡M参键的化学活性,全文包括R_2M_2(CO)_4的合成及结构,M≡M叁键与亲核试剂、与碳-碳重键,与氧或与金属羰基物等试剂的反应及其应用。
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| 关 键 词： | VIB族金属 金属-金属叁键 含羰基和环戊二烯基配体的化合物 合成 反应 用途 |
Progress in VIB Metal-Metal Triply Bonded Organometallic Compounds |
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| SONG Li-Cheng,WANG Ji-Quan.Progress in VIB Metal-Metal Triply Bonded Organometallic Compounds[J].Chinese Journal of Organic Chemistry,1994(3). |
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| Authors: | SONG Li-Cheng WANG Ji-Quan |
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| Abstract: | In this article the recent progress in research of an important class of VIB metal-metal triply bonded compounds, R2M2(CO)4(R = Cp or substituted cyclopentadienyl, indenyl etc.), has been reviewed. The emphasis of the article is placed on chemical reactivities of the functional group M=M present in this class of compounds. Topics discussed in this article includes synthesis and structures of R2M2(CO)4, the reactions of its metal-metal triple bond with various reagents (such as nucleophiles, carbon-carbon multiple bond compounds, oxygen molecule and metal carbonyls etc.), and some of their applications. ' |
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| Keywords: | VI B metal metal-metal triple bond compounds with both carbonyl and cyclo-pentadienyl synthesis reactions applications |
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