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Thorpe-Ingold effect on the conformation and photophysical properties of dialkylsilylene-spaced divinylarene copolymers
Authors:Yeh Mei-Yu  Lin Hsin-Chieh  Lee Shern-Long  Chen Chun-Hsien  Lim Tsong-Shin  Fann Wunshain  Luh Tien-Yau
Institution:Department of Chemistry, National Taiwan University, Taipei, Taiwan 106.
Abstract:Geminal disubstitution on silicon in dialkylsilylene-spaced divinylarene copolymers may dictate the conformation and photophysical properties of the copolymers, bulky (i)Pr substituted copolymers being more folded than Me substituent analogues.
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