Thorpe-Ingold effect on the conformation and photophysical properties of dialkylsilylene-spaced divinylarene copolymers |
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Authors: | Yeh Mei-Yu Lin Hsin-Chieh Lee Shern-Long Chen Chun-Hsien Lim Tsong-Shin Fann Wunshain Luh Tien-Yau |
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Institution: | Department of Chemistry, National Taiwan University, Taipei, Taiwan 106. |
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Abstract: | Geminal disubstitution on silicon in dialkylsilylene-spaced divinylarene copolymers may dictate the conformation and photophysical properties of the copolymers, bulky (i)Pr substituted copolymers being more folded than Me substituent analogues. |
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