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Spectroscopic and Structural Study of the 1:2 Aluminium(III) Complex of Quercetin
引用本文:Tian Le LIN,Bao Zhen YAN,Gao Fei HU,Mei WANG School of Science,Beijing University of Chemical Technology,Beijing 100029. Spectroscopic and Structural Study of the 1:2 Aluminium(III) Complex of Quercetin[J]. 中国化学快报, 2006, 0(7)
作者姓名:Tian Le LIN  Bao Zhen YAN  Gao Fei HU  Mei WANG School of Science  Beijing University of Chemical Technology  Beijing 100029
作者单位:Tian Le LIN,Bao Zhen YAN,Gao Fei HU,Mei WANG School of Science,Beijing University of Chemical Technology,Beijing 100029
摘    要:Quercetin (3, 3’, 4’, 5, 7-pentahydroxyflavone) is one of the most common flavonols present in nature. The complexation of Al(III) by various flavonoids has been suggested to reduce the overload of aluminum in the diet, a metal which has been implicated…


Spectroscopic and Structural Study of the 1:2 Aluminium(III) Complex of Quercetin
Tian Le LIN,Bao Zhen YAN,Gao Fei HU,Mei WANG School of Science,Beijing University of Chemical Technology,Beijing. Spectroscopic and Structural Study of the 1:2 Aluminium(III) Complex of Quercetin[J]. Chinese Chemical Letters, 2006, 0(7)
Authors:Tian Le LIN  Bao Zhen YAN  Gao Fei HU  Mei WANG School of Science  Beijing University of Chemical Technology  Beijing
Affiliation:Tian Le LIN,Bao Zhen YAN,Gao Fei HU,Mei WANG School of Science,Beijing University of Chemical Technology,Beijing 100029
Abstract:Complex formation between aluminium and quercetin(Q) in methanol was investigated by means of 27Al solid-state,13C and 1H NMR and MS(ESI),UV and IR spectra. Formation of the 1:2 complex was favored in methanol relative to all other solvent and the predominant species observed of Al(III) has a 1:2 stoichiometry. The fine structure of 1:2 aluminum complex of quercetin was that the aluminum central atom chelated with two quercetin molecules and two methoxyl groups between two five membered rings,its coordination is six,the chelated site was 3-hydroxy-4-carbonyl.
Keywords:Quercetin  Al(III) complexation  stoichiometry  NMR.
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