Poly[[[diaquazinc(II)]‐bis(μ2‐3‐cyano‐4‐dicyanomethylene‐5‐oxo‐4,5‐dihydro‐1H‐pyrrol‐2‐olato‐κ2N3:N3′)] dihydrate] |
| |
Authors: | Viktor A Tafeenko Vladimir V Chernyshev |
| |
Abstract: | The coordination of the 3‐cyano‐4‐dicyanomethylene‐5‐oxo‐4,5‐dihydro‐1H‐pyrrol‐2‐olate anion to ZnII, the apical sites of which are occupied by two water molecules, results in the formation of two‐dimensional layers of the title coordination polymer, {Zn(C8HN4O2)2(H2O)2]·2H2O}n, in which the ZnII cations lie on inversion centres in space group C2/c, with water ligands in the apical sites of octahedral geometry. Hydrogen bonds between coordinated and lattice water molecules, and π–π stacking interactions between the anions link adjacent layers into a continuous framework. |
| |
Keywords: | |
|
|