Azinyl sulfides. LXXXI. 14‐Phenyl‐7‐thiapyrano[2,3‐c;6,5‐c′]diquinoline‐14‐carbonitrile |
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Authors: | Cé line Besnard,Christian Kloc,Theo Siegrist,Christer Svensson,Krystian Pluta |
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Abstract: | The molecules of the title compound, C26H15N3S, have a pentacyclic ring system which is almost planar, with the central ring in a flattened boat conformation. The folding angle between the two quinoline rings is 6.75 (7)°. The 14‐phenyl substituent is in a quasi‐axial conformation, while the 14‐cyano substituent is in a quasi‐equatorial conformation with respect to the thiopyran ring. The S⋯C—Cphenyl and S⋯C—CCN angles are 116.8 (2) and 129.3 (2)°, respectively. The plane of the phenyl group is nearly coplanar with the plane bisecting the dihedral angle of the pentacyclic ring system. |
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