N,N′,N′′‐Tris(p‐methoxyphenyl)phosphoric triamide |
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Authors: | Chenguang Li Daniel J. Dyer Nigam P. Rath Paul D. Robinson |
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Abstract: | The title compound, C21H24N3O4P, is a self‐complementary hydrogen‐bond (HB) building unit, with (P=)O as the primary HB acceptor and N—H as the HB donor. Each of the four crystallographically distinct and nearly parallel molecules of the unit cell has a net dipole moment along the P=O bond direction and all of the dipoles are directed in the same general crystallographic direction. Head‐to‐tail N—H⋯O=P double‐HB strands stack adjacent molecules into one‐dimensional infinite polar columns. Each polar column is a 21 helix and all columns are essentially parallel, resulting in polar order throughout the entire crystal. |
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