Di‐μ‐acetato‐bis{[2,4‐dichloro‐6‐(2‐pyridylmethyliminomethyl)phenolato]zinc(II)} and di‐μ‐thiocyanato‐bis{[2,4‐dichloro‐6‐(2‐pyridylmethyliminomethyl)phenolato]copper(II)} |
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Authors: | Zhong‐Lu You |
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Abstract: | The two title complexes, Zn2(C13H9Cl2N2O)2(C2H3O2)2], (I), and Cu2(C13H9Cl2N2O)2(NCS)2], (II), are dinuclear Schiff base compounds. Both molecules are located on crystallographic centres of inversion. In (I), the ZnII atom is five‐coordinated in a trigonal–bipyramidal coordination, with one imine N atom of one Schiff base and two acetate O atoms defining the basal plane, and one O atom and one pyridine N atom of the Schiff base occupying the axial positions, while in (II), the CuII atom is five‐coordinated in a square‐pyramidal coordination, with one O and two N atoms of one Schiff base and one terminal N atom of a bridging thiocyanate ligand defining the basal plane, and one terminal S atom of another bridging thiocyanate ligand occupying the apical position. The different bridging ligands lead to the different coordinations of the complexes. |
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