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4‐[2‐(4‐Cyano­phenyl)ethenyl]‐N‐methyl­pyridinium tetra­phenyl­borate
Authors:Dan Jin  De‐Chun Zhang
Abstract:In the title compound, C15H13N2+·C24H20B?, the pyridyl ring of the cation makes a dihedral angle of 1.6° with the benzene ring. Each is rotated in the same direction with respect to the central –C—CH=CH—C– linkage, by 3.8 and 5.3°, respectively. The anions have a slightly distorted tetra­hedral geometry. Mol­ecular packing analysis was carried out using the packing energy portioning scheme in the program OPEC. Around each anion in the crystal structure there are eight anions, which inter­act with the central anion through C—H?π inter­actions. The cations are hydrogen bonded in a head‐to‐tail fashion, forming chains along 10].
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