catena‐Poly[[bis[μ‐2,4‐dichloro‐6‐(2‐pyridylmethyliminomethyl)phenolato]dicadmium(II)]‐di‐μ‐thiocyanato] |
| |
Authors: | Zhong‐Lu You |
| |
Abstract: | The title complex, [Cd2(C13H9Cl2N2O)2(NCS)2]n, is a novel thiocyanate‐bridged polynuclear cadmium(II) compound. The CdII atom is six‐coordinated in a distorted octahedral configuration, with one O and two N atoms of one Schiff base molecule and one terminal S atom of a bridging thiocyanate ligand defining the equatorial plane, and one terminal N atom of another bridging thiocyanate ligand and one O atom of another Schiff base molecule occupying axial positions. Adjacent inversion‐related [2,4‐dichloro‐6‐(2‐pyridylmethyliminomethyl)phenolato]cadmium(II) moieties utilize bridging phenolate and thiocyanate groups to form polymeric chains running along the b axis. |
| |
Keywords: | |
|
|