catena‐Poly[[diaquabis(5‐carboxypentanoato‐κO)cobalt(II)]‐μ‐1,2‐di‐4‐pyridylethane‐κ2N:N′] |
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Authors: | Hong‐Zhen Xie Dan‐Yi Wei Yue‐Qing Zheng |
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Abstract: | The title compound, [Co(C6H9O4)2(C12H12N2)(H2O)2]n, crystallizes in the space group P. The Co atom is on a center of symmetry and the 1,2‐di‐4‐pyridylethane (bpe) ligand also sits across a crystallographic inversion center. The Co atom is octahedrally coordinated by two aqua ligands, two carboxylate O atoms and two pyridyl N atoms, and is bridged by the anti‐bpe ligands to generate one‐dimensional {[Co(Hadip)2(H2O)2](bpe)2/2} chains (Hadip is 5‐carboxypentanoate), which are further interlinked by O—H⋯O and C—H⋯O hydrogen bonds into two‐dimensional layers. |
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