fac‐Bromotricarbonyl[2‐(2‐pyridylmethyl)‐2,3‐dihydro‐1H‐isoindol‐1‐one]rhenium(I) methanol solvate |
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Authors: | Lihui Wei Jon Zubieta |
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Abstract: | The structure of the title compound, fac‐[ReBr(C14H12N2O)(CO)3]·CH4O, consists of neutral mononuclear molecular units of distorted octahedral geometry, with the three carbonyl donors in a facial orientation. The remaining coordination sites are occupied by the Br atom, the pyridine N atom and the ketone O‐atom donor of the ligand. The molecules pack in stacks of antiparallel tapes, with a network of classical (O—H⋯Br) and non‐classical (C—H⋯O) hydrogen bonds between the methanol solvent molecule and the complex molecule. |
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