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Bis(thio­carbohydrazide)dithio­cyanato­iron(II)
Authors:Guang‐Qi Xiang  Wei‐Dong Wang  Mao‐Lin Hu  Zhi‐Min Jin  Ya‐Ping Lü
Abstract:In the title compound, FeII(NCS)2(CH6N4S)2], the FeII cation is surrounded by two S atoms and two N atoms from thio­carbohydrazide groups and by two N atoms from thio­cyanate groups. The geometry around the FeII cation, which is located on a center of inversion, is distorted octa­hedral. The thio­carbohydrazide mol­ecule assumes a cistrans conformation, which is reinforced by an N—H?N hydrogen bond. Mol­ecules of the title compound are connected via inter­molecular N—H?S and N—H?N hydrogen bonds to form a three‐dimensional network structure.
Keywords:
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