Abstract: | In the title compound, FeII(NCS)2(CH6N4S)2], the FeII cation is surrounded by two S atoms and two N atoms from thiocarbohydrazide groups and by two N atoms from thiocyanate groups. The geometry around the FeII cation, which is located on a center of inversion, is distorted octahedral. The thiocarbohydrazide molecule assumes a cis–trans conformation, which is reinforced by an N—H?N hydrogen bond. Molecules of the title compound are connected via intermolecular N—H?S and N—H?N hydrogen bonds to form a three‐dimensional network structure. |