(μ‐2,11‐Dithia[3.3]paracyclophane‐κ2S:S′)bis[(6‐carboxypyridine‐2‐carboxylato‐κ2N,O6)silver(I)]: a mixed‐ligand silver‐based dinuclear compound |
| |
Authors: | Shu‐Qin Liu Hisashi Konaka Takayoshi Kuroda‐Sowa Gui‐Ling Ning Megumu Munakata |
| |
Abstract: | In the title complex, Ag2(C7H4NO4)2(C16H16S2)], each AgI atom is trigonally coordinated by one S atom of a 2,11‐dithia3.3]paracyclophane (dtpcp) ligand, and by one N and one O atom of a 6‐carboxypyridine‐2‐carboxylate ligand. Dtpcp acts as a bidentate ligand, bridging two inversion‐related AgI atoms to give a dinuclear silver(I) compound. The dinuclear moieties are interconnected via O—H·O hydrogen bonds to form a two‐dimensional zigzag sheet. Two such sheets are interwoven viaπ–π interactions between pyridine rings, affording an interwoven bilayer network. |
| |
Keywords: | |
|
|