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(μ‐2,11‐Dithia­[3.3]paracyclo­phane‐κ2S:S′)bis­[(6‐carboxy­pyridine‐2‐carboxylato‐κ2N,O6)silver(I)]: a mixed‐ligand silver‐based dinuclear compound
Authors:Shu‐Qin Liu  Hisashi Konaka  Takayoshi Kuroda‐Sowa  Gui‐Ling Ning  Megumu Munakata
Abstract:In the title complex, Ag2(C7H4NO4)2(C16H16S2)], each AgI atom is trigonally coordinated by one S atom of a 2,11‐dithia­3.3]paracyclo­phane (dtpcp) ligand, and by one N and one O atom of a 6‐carboxy­pyridine‐2‐carboxylate ligand. Dtpcp acts as a bidentate ligand, bridging two inversion‐related AgI atoms to give a dinuclear silver(I) compound. The dinuclear moieties are inter­connected via O—H·O hydrogen bonds to form a two‐dimensional zigzag sheet. Two such sheets are inter­woven viaπ–π inter­actions between pyridine rings, affording an inter­woven bilayer network.
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