[μ‐N,N′‐Bis(2‐aminoethyl)oxamidato(2–)]bis[(4,5‐diazafluoren‐9‐one)perchloratocopper(II)] 4,5‐diazafluoren‐9‐one disolvate |
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Authors: | Yan‐Ping Li Pin Yang Zi‐Xiang Huang Fu‐Xin Xie |
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Abstract: | The title compound, Cu2(C6H12N4O2)(ClO4)2(C11H6N2O)2]·2C11H6N2O, contains a dinuclear copper(II) complex which lies about a twofold axis at the mid‐point of the C—C bond of the oxamide ligand that bridges the two CuII atoms. The Cu·Cu distance is 5.215 (2) Å and the Cu atoms have distorted octahedral coordination geometry. Intramolecular N—H·O and N—H·N hydrogen bonds and intermolecular C—H·O hydrogen bonds, together with π–π stacking interactions, dominate throughout the crystal structure. |
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