catena‐Poly[[bis[aqua(1,10‐phenanthroline)lead(II)]‐di‐μ3‐5‐carboxy‐3‐sulfonatobenzoato] dihydrate] |
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Authors: | Mao‐Lin Hu Xin‐Hua Li Hong‐Ping Xiao Qiao Zhang |
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Abstract: | In the centrosymmetric title polymer, catena‐poly[[bis[aqua(1,10‐phenanthroline‐κ2N,N′)lead(II)]‐di‐μ3‐5‐carboxy‐3‐sulfonatobenzoato‐1:2:1′κ4O3:O1,O1′:O1;2′:1:2κ4O1:O1,O1′:O3] dihydrate], {[Pb(C8H4O7S)(C12H8N2)(H2O)]·H2O}n, each seven‐coordinate lead(II) ion is bound by five O atoms from one water molecule and three 5‐sulfoisophthalate (sip) anions, and by two N atoms from a 1,10‐phenanthroline (phen) ligand. The sip sulfonate group is monodentate. One O atom of the sip carboxylate group is chelated to one Pb2+ cation, with the other also bridging an adjacent Pb2+ cation. The carboxyl group is uncoordinated. This unusual coordination results in a chain structure along the b axis, which is linked by strong intermolecular hydrogen bonds into a three‐dimensional network. |
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