Concomitant transient electrochemical and spectroscopic detection with electron pulse radiolysis期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Concomitant transient electrochemical and spectroscopic detection with electron pulse radiolysis

Affiliation:	1. Laboratoire Interfaces et Systèmes Electrochimiques, UPMC Univ Paris 06, UPR 15 du CNRS, 4 place Jussieu, 75005 Paris, France;2. Laboratoire de Chimie Physique/ELYSE, UMR 8000 CNRS/Université Paris-Sud 11, Faculté des Sciences d''Orsay, Bât. 349, 91405 Orsay Cedex, France;1. Department of Molecular Medicine, University of Padova and Istituto Nazionale Biostrutture Biosistemi, Italy;2. Istituto Nazionale Biostrutture e Biosistemi, Italy;3. Department of Physics, University of Trento and Istituto Nazionale Biostrutture e Biosistemi, Italy

Abstract:	The possibility to couple a transient electrochemical detection of the redox intermediates produced by a picosecond electron accelerator is explored. The principle is demonstrated with the well-behaved methylviologen radical cation that can be reoxidised at the electrode and simultaneously detected by transient absorption.

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