Enhanced performance of SiO/Fe2O3 composite as an anode for rechargeable Li-ion batteries |
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Affiliation: | 1. College of Materials and Energy, South China Agricultural University, Guangzhou, Guangdong 510642, China;2. College of Material science Engineering, Center South University, Changsha, Hunan 410083, China;1. College of Materials Science and Engineering, Hunan Province Key Laboratory for Advanced Carbon Materials and Applied Technology, Hunan University, Changsha 410082, China;2. State Key Laboratory of Advanced Design and Manufacturing for Vehicle Body, Hunan University, Changsha 410082, China |
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Abstract: | Iron oxide (Fe2O3) was utilized to enhance the electrochemical properties of SiO as a promising anode for Li-ion batteries. An SiO/Fe2O3 composite, composed of SiO coated with Fe2O3 nanoparticles, was synthesized by mechanical milling and characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and energy-dispersive X-ray spectroscopy. The electrochemical properties of the SiO/Fe2O3 composite, SiO, and mechanically milled SiO as anodes for Li-ion batteries were then investigated. The SiO/Fe2O3 composite showed superior performance compared with the two Fe2O3-free SiO samples, including an increased initial coulombic efficiency, enhanced rate capability, and better capacity retention. |
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