Poly[nickel(II)‐di‐μ‐4,4′‐bipyridyl‐κ4N:N′‐μ‐dichromato‐κ2O:O′] and poly[copper(II)‐di‐μ‐4,4'‐bipyridyl‐κ4N:N′‐μ‐dichromato‐κ2O:O′] |
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Authors: | Amy L Kopf Paul A Maggard Charlotte L Stern Kenneth R Poeppelmeier |
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Abstract: | The novel title hybrid isomorphous organic–inorganic mixed‐metal dichromates, Ni(Cr2O7)(C10H8N2)2] and Cu(Cr2O7)(C10H8N2)2], have been synthesized. A non‐centrosymmetric three‐dimensional (4,6)‐net is formed from a linear chain of vertex‐linked Cr2O]2? and MN4O]2+ (M = Ni and Cu) units, which in turn are linked by the planar bidentate 4,4′‐bipyridine ligand through the four remaining vertices of the MN4O]2+ octahedra. There are two such three‐dimensional nets that interpenetrate with inversion symmetry. |
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