Tri‐μ2‐chloro‐tetrachloro‐μ3‐oxo‐hexakis(tetrahydrofuran‐κO)dititanium(III)samarium(III): a novel trinuclear Sm–Ti mixed species |
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Authors: | Claude Villiers,Michel Ephritikhine,Pierre Thué ry |
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Abstract: | In the title compound, [SmTi2Cl7O(C4H8O)6], the metal ions are linked by a central μ3‐oxo ion and by three μ2‐chloro ions, giving a planar moiety containing a binary crystallographic axis. The coordination spheres are completed by terminal chloro ligands and tetrahydrofuran molecules, with resulting pentagonal bipyramidal and octahedral environments for the Sm and Ti atoms, respectively. |
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