Crystal assembly based on 3,5-bis(2′-benzimidazole) pyridine and its complexes |
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| Institution: | 1. College of Light Industry & Chemical Engineering, Guangdong University of Technology, Guangzhou 510006, PR China;2. Logistics Group, Huainan Normal College, Huainan 232038, PR China;1. School of Medicine and Life Sciences, University of Jinan-Shandong Academy of Medical Sciences, Jinan 250200, Shandong, China;2. Institute of Materia Medica, Shandong First Medical University & Shandong Academy of Medical Sciences, Jinan 250062, Shandong, China;3. Key Laboratory for Biotech-Drugs Ministry of Health, Jinan 250062, Shandong, China;4. Key Laboratory for Rare ＆ Uncommon Diseases of Shandong Province, Jinan 250062, Shandong, China;5. Laboratory, Generic Manufacture Technology of Chinese Traditional Medicine, Jinan, China;6. Center for New Drug Pharmacological Research of Lunan Pharmaceutical Group, Jinan, China;1. Department of Chemistry, Tsinghua University, Beijing, 100084, PR China;2. The State Key Laboratory of Chemical Oncogenomics, Key Laboratory of Chemical Biology, The Graduate School at Shenzhen, Shenzhen, 518055, PR China;3. Key Lab of Optoelectronics Devices and Systems of Ministry of Education and Guangdong Province, College of Physics and Optoelectronic Engineering, Shenzhen University, Shenzhen 518060, PR China;4. National & Local United Engineering Lab for Personalized Anti-tumor Drugs, Shenzhen Kivita Innovative Drug Discovery Institute, The Graduate School at Shenzhen, Tsinghua University, Shenzhen 518055, PR China;5. Department of Pharmacology and Pharmaceutical Sciences, School of Medicine, Tsinghua University, Beijing, 100084, PR China;1. Centro Conjunto de Investigación en Química Sustentable, UAEM-UNAM, Toluca, Estado de México, México;2. Universidad Nacional Autónoma de México, Mexico City, Mexico;1. Centre for Nanoscience and Nanotechnology (UIEAST), Panjab University, Chandigarh 160014, India;2. Department of Chemistry, Indian Institute of Technology Ropar (IIT Ropar), Rupnagar, Panjab 140001, India;1. Department of Chemical and Biomolecular Engineering, 50 Yonsei-ro, Seodaemun-gu, Seoul 120-749, Republic of Korea;2. National Center for Inter-University Research Facilities, Seoul National University, 1 Gwanak-ro, Gwanak-gu, Seoul 151-742, Republic of Korea |
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| Abstract: | Imdazole, pyridine and their derivatives have been considered as excellent ligands in supramolecular self-assembly. In this paper, a ligand molecule 3,5-bis (2′-benzimidazole) pyridine (BBP) was prepared, and two different crystal architectures based on the ligand molecule were self-assembled by diffusion/solvothermal ways. Furthermore, several crystal architectures of several relative complexes were also successfully assembled. These crystal structures were well defined by X-ray diffractions. Structural resolutions indicated that, as building blocks, this bibenzimidazole pyridine molecules exhibited coordination varieties in constructing the crystal architectures based on its related complexes. |
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