首页 | 本学科首页   官方微博 | 高级检索  
     检索      


A novel thio­cyanate‐bridged dinuclear cadmium(II) complex: di‐μ‐thio­cyanato‐bis­((methanol){4‐nitro‐2‐[2‐(dimethyl­amino)ethyl­imino­meth­yl]phenolato}cadmium(II))
Authors:Zhong‐Lu You  Hai‐Liang Zhu
Abstract:The title complex, Cd2(C11H14N3O3)2(NCS)2(CH4O)2], is an inter­esting thio­cyanate‐bridged dinuclear cadmium(II) compound. It is located on a crystallographic inversion center. The CdII atom is six‐coordinated in an octa­hedral configuration by one O and two N atoms of one Schiff base ligand and by the terminal N atom of a bridging thio­cyanate ligand, defining the basal plane, and by the terminal S atom of another bridging thio­cyanate ligand and by the O atom of a coordi­nated methanol mol­ecule, occupying the axial positions. The mol­ecules are linked through inter­molecular O—H⋯O hydrogen bonds, forming chains running along the b axis.
Keywords:
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号