Abstract: | The title complex, Cd2(C11H14N3O3)2(NCS)2(CH4O)2], is an interesting thiocyanate‐bridged dinuclear cadmium(II) compound. It is located on a crystallographic inversion center. The CdII atom is six‐coordinated in an octahedral configuration by one O and two N atoms of one Schiff base ligand and by the terminal N atom of a bridging thiocyanate ligand, defining the basal plane, and by the terminal S atom of another bridging thiocyanate ligand and by the O atom of a coordinated methanol molecule, occupying the axial positions. The molecules are linked through intermolecular O—H⋯O hydrogen bonds, forming chains running along the b axis. |